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class="xypg-detail-title">氨逃逸治理何成為煙氣氨法脫硫治理中的老大難</h1> <div class="xypg-detail-info-bar"> <div class="detail-info-time"><i class="icon-font icon-shijian"></i>2021-04-26 09:59:18</div> <div class="detail-info-numbers"><i class="icon-font icon-chakan"></i><script src="http://www.oheliza.com/source/include/browse.php?model=news&id=459"></script>次</div> </div> <div class="xypg-detail-con"><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;"><a href='http://www.oheliza.com/' target='_blank' class='key_tag'><font><strong>氨逃逸治理</strong></font></a>的工藝原理</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">氨法脫硫是氣液兩相之間相互傳質傳熱并發生化學反應的過程。</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">在整個脫硫反應中，(NH4)2SO3對SO2的吸收起主要作用，隨著反應的進行，(NH4)2SO3濃度會逐漸下降，NH4HSO3濃度逐漸上升。為了保持脫硫循環液的吸收能力，需要向漿液池中注入氨水使NH4HSO3轉化為(NH4)2SO3，為了避免生成的(NH4)2SO3重新分解成SO2，(NH4)2SO3被氧化風機鼓入的氧化空氣強制氧化成為(NH4)2SO4。</span></p><p style="text-align:center"><img src="http://cdn.myxypt.com/fcb22fc3/21/04/ca48ca5e4d0bea80bca7319515e599bf7c43f140.jpg" width="500" height="400" border="0" vspace="0" title="氨逃逸治理" alt="氨逃逸治理" style="width: 500px; height: 400px;"/></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">什么是氨逃逸？</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">氨逃逸專指氣態氨隨煙氣排出脫硫裝置的現象。在氨法脫硫工程中，通常造成氨逃逸的主要原因是脫硫循環液中游離氨含量高。氨是極易揮發的物質，常溫常壓下氨是氣體。所以在氨法脫硫的工程中需要將氨的濃度和溫度降到盡量低。脫硫所需要的氨是由脫除煙氣中的二氧化硫的量所決定的，所以為了使吸收液中氨的濃度降低，只能加大吸收液的循環量，同時，吸收液溫度降低。</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">另外，亞硫酸銨氧化率低也是造成氨逃逸嚴重的另一個原因。脫硫生成的亞硫酸銨是不穩定的化合物，如果不及時氧化成穩定的硫酸銨，容易分解成二氧化硫和氨，造成排放煙氣中二氧化硫升高同時氨逃逸加劇。</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">隨著氨法脫硫工藝的日趨成熟及普遍應用，氨逃逸現象也發展成為治理痛點，甚至有地方出臺的治氣方案中明文規定——在采用氨法脫硫工藝時，氨逃逸率濃度須小于8毫克/立方米。</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">該技術在裝置上，對諸多工藝參數進行了調優試驗，找出了影響SO2吸收效率及氨逃逸的主要原因。</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">（1）嚴格控制氧化段的亞硫酸銨的氧化效率達到99.8%以上；</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">（2）嚴格控制加氨后吸收液的pH值（5~5.5），保證SO2吸收率達到99.5%以上；</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">（3）找到較佳的加氨位置，研發了泵前加氨室，合理控制加氨量，從而控制吸收段中氨量極低，保證排放凈煙氣氨逃逸量在1.0mg/Nm3以下,實測值為0.43 mg/Nm3。</span></p><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px;">解決了氨逃逸，不僅提升了脫硫效率，更節約了運行成本，氨法脫硫工藝在今后的工業治氣中必然會應用更廣，助力工業生產實現綠色生態循環模式。</span></p></div> <div class="xypg-detail-tags"> <div class="tags-title"> <h3>標簽</h3> <div class="baidu-share">  <div class="bdsharebuttonbox"> <a href="#" class="bds_more" data-cmd="more"></a> <a href="#" class="bds_qzone" data-cmd="qzone" title="分享到QQ空間"></a> <a href="#" class="bds_tsina" data-cmd="tsina" title="分享到新浪微博"></a> <a href="#" class="bds_tqq" data-cmd="tqq" title="分享到騰訊微博"></a> <a href="#" class="bds_renren" data-cmd="renren" title="分享到人人網"></a> <a href="#" class="bds_weixin" data-cmd="weixin" title="分享到微信"></a> </div> 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