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class="xypg-detail-title">scr脫硝效率低是因為什么？</h1> <div class="xypg-detail-info-bar"> <div class="detail-info-time"><i class="icon-font icon-shijian"></i>2022-11-25 10:50:40</div> <div class="detail-info-numbers"><i class="icon-font icon-chakan"></i><script src="http://www.oheliza.com/source/include/browse.php?model=news&id=516"></script>次</div> </div> <div class="xypg-detail-con"><p style="text-indent: 2em;"><br/></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">scr<a href='http://www.oheliza.com/news/443.html' target='_blank' class='key_tag'><font><strong>脫硝工藝</strong></font></a>系統主要包括煙氣系統、氨水儲存及供應系統、氨水直噴系統、SCR反應器、SCR催化劑、吹灰及控制系統等部分。氮氧化物（NOx）在催化劑的作用下，選擇性催化還原過程是通過添加氨（NH3）可以把NOx轉化為空氣中自然含有的氮氣（N2)和水，因為NH3可以“選擇性的”和NOx反應不是氧氣（O2)氧化，因此反應被稱為具有“選擇性”。主要方程式如下；</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;"><br/></span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">除上述反應外，條件變化時還可能發生以下副反應；</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">影響<a href='http://www.oheliza.com/' target='_blank' class='key_tag'><font><strong>scr脫硝</strong></font></a>性能的主要因素</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">1、催化劑的活性</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">催化劑的活性是指催化劑的催化能力，是指某一特定催化劑對反應速率的影響程度。目前市場上主流催化劑有三種，分別為蜂窩式、平板式與波紋板式。催化劑是SCR技術的核心，scr脫硝廣泛應用的催化劑主要成分為V2O5/TiO2。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">催化劑活性喪失的主要原因是SCR在實際操作過程中，由于煙氣中的某些成分導致催化劑中毒，催化劑燃燒導致煙氣溫度過高，催化劑因飛灰的影響而磨損。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;"><br/></span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">2、催化劑中毒</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">催化劑的中毒主要為堿金屬（、）中毒。由于鈉等可溶性堿金屬鹽的堿性比NH3大，賤金屬鹽與催化劑活性成分反應，造成催化劑中毒，引起催化劑活性降低。對于堿性金屬中毒，由于堿性金屬在水溶性下具有很強的活性，它會完全滲透到催化劑材料中，因此可以有效避免水蒸氣在催化劑表面凝結。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;"><br/></span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">3、飛灰引起催化劑中毒</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">催化劑的堵塞主要是由于銨鹽及飛灰的小顆粒沉積在催化劑小孔，阻礙NOX、NH3、O2到達催化劑活性表面，引起催化劑鈍化?？梢酝ㄟ^調節氣流分布，選擇合理的催化劑間距和單元空間，并使進入SCR反應器煙氣的溫度維持在銨鹽沉積溫度之上，以防止催化劑堵塞。為保證催化劑通道暢通，采用脈沖吹灰。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;"><br/></span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">4、催化劑的侵蝕、磨蝕</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">催化劑的侵蝕和磨損主要是由于催化劑表面飛灰的沖擊。磨蝕強度與氣流速度、飛灰特性、撞擊角度及催化劑本身特性有關。大多數催化劑研磨發生在催化劑邊緣，直接暴露于粉塵顆粒的影響下，以減少研磨措施：首先，使用耐腐蝕催化劑材料處理催化劑頂部，以提高催化劑邊緣的硬度；其次，利用計算流體動力流模型優化氣流分布；第三，在垂直催化劑床上安裝氣流調節裝置。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;"><br/></span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">5、煙氣溫度</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">煙氣溫度既決定了催化還原反應的速度，也決定了催化劑的活性。催化劑的活性與煙氣溫度的關系如圖2所示。煙氣溫度為340℃～380℃之間時，V2O5活性高，即催化劑活性高。當煙氣溫度較低，不僅催化劑活性降低，而且噴入的還原劑NH3與S03反應生成硫酸銨，附著在催化劑表面；當煙氣溫度較高，噴入的還原劑NH3與02反應生成NOx抵消了脫硝效果。催化劑長期暴露于450℃在上述高溫環境中，催化劑活性部位的燒結會導致催化劑顆粒增大，表面積減小，催化劑活性降低。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">煙氣溫度主要隨鍋爐負荷的變化而變化，因此爐負荷應盡可能穩定。在催化劑制作工藝上適量加入鎢進行退火處理，可以減少催化劑的燒結。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">6、SO2/SO3轉化率</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">催化劑中的V2O5不僅是重要的活性成分，具有較高的脫硝效率，但同時也能促進SO2向S03轉化，SO2/S03轉化率與溫度的關系如圖3所示。煙氣溫度下降到232℃當水蒸氣存在時，下面，SO3會與噴入的NH硫酸銨產生硫酸銨，沉積在催化劑表面，導致催化劑堵塞。如果煙氣溫度降至110℃以下，S與水的反應完全生成H2SO4，煙氣中的H2SO蒸汽濃度是影響煙氣酸露點的決定性因素之一，即使其含量很小，煙氣酸露點也會急劇上升。當溫度降低到酸露點以下時,就會有硫酸液滴析出,造成空氣預熱器的冷端受熱面結露,腐蝕、堵灰。本工程SCR裝置中S0./SO,轉化率一般限制在1%以下。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;"><br/></span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">7、NH3的逃逸</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">在SCR系統中，催化劑是分層布置的，而NH的泄漏是由于分布不均造成的。當SCR多余的反應器沒有參與反應NH與SO3體積濃度比超過2:1時，在水蒸氣的作用下產生體積濃度比NH4HSO4。NH4HSO4是一種附著力強、腐蝕性強的物質，吸附性強，造成堵塞。同時NH3過剩導致飛灰化學性質發生變化，飛灰質量惡化，再利用率降低，運行成本增加。本工程SCR裝置中，NHI的逃逸控制在5ppm以下。</span></p><p style="text-indent: 2em;"><span style="font-family: 宋體, SimSun; font-size: 16px;">為了使<a href='http://www.oheliza.com/news/443.html' target='_blank' 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